Anmol Chemicals is the pioneer manufacturers of Sodium Sulfide, Pharmaceutical Excipients Fragrance & Flavor chemicals in India. We offer Halal and Kosher Sodium Sulfide made in an ISO9001:2008, ISO22000:2005 (FSSC22000) and cGMP certified facility. Our group has several manufacturing facilities spread across the world, supported by toll manufacturers and representatives in UAE, Europe, Africa, USA, China and has several associated manufacturing facilities spread across India. All the Information on Physics, Chemistry, Applications, Uses and Technology on Manufacture of Sodium Sulfide is in these pages.

The units have one or more of the certifications like FDA GMP, ISO 9001, ISO 22000, HACCP, REACH, Kosher & Halal

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Sodium Sulfide Nonahydrate SDS GHS, MSDS Sheet

Specifications of Sodium Sulfide

Sodium Sulfide Nonahydrate SDS GHS, MSDS Sheet, Material Safety Data Sheet

1. Product Identification

Synonyms: Sodium monosulfide nonahydrate; Sodium sulphide nonahydrate
CAS No.: 1313-84-4
EINECS EC-No.: 215-211-5
Molecular Weight: 240.18
Chemical Formula: Na2S.9H20
Recommended usage: Industrial Manufacturing.
Suppliers: As per letterhead above.

2. Hazards Identification

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Acute toxicity, Oral (Category 4) H302
Acute toxicity, Dermal (Category 3) H311
Skin corrosion (Category 1B) H314
Acute aquatic toxicity (Category 1) H400

Labeling according GHS & Regulation (EC) No 1272/2008

GHS Label Elements
Toxic
Toxic

GHS Label Elements
Corrosive
Corrosive

GHS Label Elements
Marine Pollutant
Aquatic Toxicity

Signal Words: Danger

Hazard statements:
H302: Harmful if swallowed.
H311: Toxic in contact with skin.
H314: Causes severe skin burns and eye damage.
H400: Very toxic to aquatic life.

Precautionary statements:
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P262: Do not get in eyes, on skin, or on clothing.
P264: Wash skin thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P273: Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P362: Take off contaminated clothing and wash before reuse.
P301+P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302+P352: IF ON SKIN: Wash with soap and water.
P303+361+353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304+340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P314: Get Medical advice/attention if you feel unwell.
P330: Rinse mouth.
P301+330+331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P332+P313: If skin irritation occurs: Get medical advice/attention.
P333+313: If skin irritation or a rash occurs: Get medical advice/attention.
P337+P313: If eye irritation persists: Get medical advice/ attention.
P360: Rinse immediately contaminated clothing and skin with plenty of water before removing clothes.
P391: Collect spillage.
P405: Store locked up.
P501: Dispose of contents/ container to an approved waste disposal plant.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
T: Toxic , C: Corrosive, Xn; Harmful, N: Dangerous for the environment
R22- Harmful if swallowed. R24- Toxic in contact with skin. R31- Contact with acids liberates toxic gas. R34- Causes burns. R50- Very toxic to aquatic organisms.
For the full text of the H-statements & R-phrases mentioned in this Section, see Section 16.

3. Composition/Information on Ingredients

Ingredient: Sodium Sulfide Nonahydrate
CAS No.: 1313-84-4
EINECS EC-No.: 215-211-5
Percent: 97 - 100%

4. First Aid Measures

Always seek medical attention after first aid measures are provided.
Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.

5. Fire Fighting Measures

Flammability of the Product: Non-flammable.
Products of Combustion: Sulphur oxides, Sodium oxides, fumes.
Fire: Sodium Sulfide Nonahydrate is not considered to be a fire hazard.
Fire Extinguishing Media: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Use water to cool fire-exposed containers.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures or when moistened under fire conditions, it may produce toxic or irritating fumes. On decomposition it may emit hydrogen sulfide. Containers may explode on heating

6. Accidental Release Measures

Small Spill: Avoid dust formation. Avoid breathing dust. Ensure adequate ventilation. Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill: Sodium Sulfide Nonahydrate is a corrosive solid. Avoid touching the spilled material. Do not let the product enter drains. Use a shovel to put the material into a convenient waste disposal container. Do not contaminate the environment.

7. Handling and Storage

Do not ingest. Do not breathe dust. Wear suitable protective clothing. In case of insufficient ventilation, wear suitable respiratory equipment.
Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Wash hands thoroughly after handling. Provide appropriate exhaust ventilation at places where dust is formed. If you feel unwell, seek medical attention.
Keep Sodium Sulfide Nonahydrate in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Keep away from incompatibles such as oxidizing agents, metals, acids.

8. Exposure Controls/Personal Protection

Airborne Exposure Limits: Not established for the product. However, if Hydrogen sulfide is released in handling and use, then observe its limits.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

9. Physical and Chemical Properties

Appearance: Sodium Sulfide Nonahydrate is yellowish powder.
Odor: rotten egg-like.
Solubility: It soluble in water.
pH: Alkaline
Density: 1.43 g/mL at 20C (68F)
Molecular Weight:
240.18
Chemical Formula: Na2S.9H20
% Volatiles by volume @ 21C (70F): -
Boiling Point: 920°C - lit.
Melting Point: 50°C - dec.

10. Stability and Reactivity

Stability: Sodium Sulfide Nonahydrate is stable under ordinary conditions of use and storage. One can say, it is moderately stable in atmospheric condition. Aqueous solutions and moist solid may slowly give off hydrogen sulfide gas.
Air and light sensitive. May discolor on exposure to air. Liberates toxic hydrogen sulfide on contact with acids. Reacts violently with carbon, diazonium salts; n,n-dichloromethylamine, o-Nitroaniline, diazonium salt, water. Reacts with water to form strong solutions and Hydrogen sulfide Reacts with acid more vigorously , producing corrosive solutions, and hydrogen sulfide. Also incompatible with Acids, Aluminum, Zinc. Decomposes in air at 920-950 deg. C.
Hazardous Decomposition Products: It emits toxic hydrogen sulfide fumes when heated to decomposition. It may form sodium oxide and sulfur.
Hazardous Polymerization: Will not occur.
Incompatibilities: Strong oxidizing agents, metals & acids.
Conditions to Avoid: Incompatibles and moisture.

11. Toxicological Information

Toxicity data
Oral LD50 Mouse: 205 mg/kg
Oral LD50 Rat: 208 mg/kg; Intraperitoneal LD50 147 mg/kg
LD50 Dermal: < 340 mg/kg ( Rabbit )
Carcinogenic Effects: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC, ACGIH, NTP, OSHA.
Mutagenic Effects: Not available.
Teratogenic Effects: Not available.
Developmental Toxicity: Not available.

12. Ecological Information

Toxicity to fish: LC50: 7.7 - 29.1 mg/L, 96h (Poecilia reticulata) for Na2S
Environmental Fate: Not available.
Environmental Toxicity: It is also toxic to fish. Harmful to aquatic life in very low concentrations. Sodium Sulfide Nonahydrate is toxic to fish and marine organisms when applied to streams, rivers, ponds or lakes.
BOD5 and COD: Not available.
Products of Biodegradation: Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.
Toxicity of the Products of Biodegradation: The products of degradation are less toxic than the product itself.
This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

13. Disposal Considerations

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements.

14. Transport Information

DOT (US) & ADI/RID:
UN number: 1849 Class: 8 Packing group: II
Proper shipping name: SODIUM SULFIDE, HYDRATED
IMDG:
UN number: 1849 Class: 8 Packing group: II
Proper shipping name: SODIUM SULFIDE, HYDRATED
IATA:
UN number: 1849 Class: 8 Packing group: II
Proper shipping name: SODIUM SULFIDE, HYDRATED

15. Regulatory Information

USA:
SARA 302
: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA 313: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minims) reporting levels established by SARA Title III, Section 313.
California Prop. 65 Components: This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.
HMIS (Perceived): Health hazard: 3, Flammability: 0, Physical hazards: 0
NFPA (Perceived): Health hazard: 3, Flammability: 0, Physical hazards: 0

Canada WHMIS Classification: E Corrosive material, D1A Very toxic materials, D2B Toxic materials, F Dangerously reactive material.

16. Other Information

EINECS EC-No.: 215-211-5
H302 = Harmful if swallowed.
H311 = Toxic in contact with skin.
H314 = Causes severe skin burns and eye damage.
H400 = Very toxic to aquatic life.
T = Toxic
C = Corrosive
Xn = Harmful
N = Dangerous for the environment
R22 = Harmful if swallowed.
R24 = Toxic in contact with skin.
R31 = Contact with acids liberates toxic gas.
R34 = Causes burns.
R50 = Very toxic to aquatic organisms.

Disclaimer:
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Our company provides this SDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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Sodium Sulfide manufacturers at:

Anmol Chemicals
S-8, SARIFA MANSION, 2ND FLANK ROAD, CHINCHBUNDER, MUMBAI 400009, INDIA
TEL: (OFFICE) 91-22-23770100, 23726950, 23774610, 23723564 - FAX: 91-22-23728264

e-mail: anmolc@mtnl.net.in

ISO9000

Exports to USA, Canada, UAE, Dubai, South Africa, Tanzania, Kenya, Nigeria, Egypt, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Europe Netherlands, Italy, Spain, Germany, Portugal, France, Malaysia, Indonesia, Thailand, Korea, Japan,etc.

Copyright and Usual Disclaimer is Applicable. 15 March, 2016

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